# methanolvwr20847

date : 2022-08-24

language_code : en

name : methanolvwr20847

ph : 7

## euh_codes

## expositions

code: H225 exposition: danger: Label elements for flammable liquids text: Liquide et vapeurs très inflammables.

code: H301 exposition: oral danger: Acute toxicity label elements text: Toxique en cas d’ingestion.

code: H311 exposition: dermal danger: Acute toxicity label elements text: Toxique par contact cutané.

code: H331 exposition: inhalation danger: Acute toxicity label elements text: Toxique par inhalation.

code: H370 exposition: danger: Label elements for specific target organ toxicity after single exposure text: Risque avéré d'effets graves pour les organes.

## h_codes

H225, H301, H311, H331, H370

## information

## p_codes

P210, P243, P280, P302+P352, P304+P340, P308+P310

## precautions

code: P210 text: P210

code: P243 text: Prendre des mesures de précaution contre les décharges électrostatiques.

code: P280 text: Porter des gants de protection/des vêtements de protection/un équipement de protection des yeux/ du visage.

code: P302+P352 text: EN CAS DE CONTACT AVEC LA PEAU:

code: P304+P340 text: EN CAS D’INHALATION:

code: P308+P310 text: EN CAS d’exposition prouvée ou suspectée:

age : 3

## body

skin : **Skin contact** • Wash the affected area immediately with plenty of water and soap. • Remove contaminated, saturated clothing right away. • If skin reactions occur, consult a physician.

eyes : **Eye contact** • Flush the eye(s) immediately with plenty of flowing water for 10–15 minutes while holding the eyelids apart. • Remove contact lenses if present and easy to do. • Continue rinsing and consult an ophthalmologist; protect the uninjured eye.

ingestion : **Ingestion** • Call a poison centre/doctor immediately. • Do **not** induce vomiting. • Rinse the mouth thoroughly with water. • Give nothing to eat or drink.

inhalation : **Inhalation** • Call a poison centre/doctor immediately. • Move the person to fresh air and keep them warm and at rest. • If breathing is irregular or stops, give artificial respiration.

## company

name : VWR International Ltd.

## fire

water : True

foam : False

powder : True

co2 : True

other : Nitrogen

## labellings

explosive : False

flammable : True

oxidising : False

gaz : False

corrosive : False

acute : True

health : False

serious : True

hazardous : False

warning : Danger

## protection

skin : -

eyes : **Eye / face protection** \| Eye glasses with side protection \| Must conform to DIN‑EN 166. Recommended model: **VWR 111‑0432**.

respiratory : **Respiratory protection** \| Full‑, half‑ or quarter‑face masks (DIN EN 136/140) \| Required when aerosol or mist formation occurs. Recommended model: **VWR 111‑0206**. Filter material: **AXP3** (recommended model: **VWR 111‑8932**).

hands : **Gloves – short‑term hand contact** \| Nitrile rubber (NBR) \| Thickness: **0.38 mm**. Breakthrough time: **not specified**. Recommended model: **VWR 112‑1381**.

**Gloves – long‑term hand contact** \| Butyl rubber (butyl caoutchouc) \| Thickness: **0.30 mm**. Breakthrough time: **> 480 min**. Recommended model: **VWR 112‑3779**.

clothing : **Protective clothing** \| CE‑labelled clothing with the four control digits \| Must be worn when handling the chemical. No further material or thickness details are given in the document.

## stability

stability : The product is chemically stable under standard ambient conditions (room temperature).

reaction : - The material is non‑reactive under normal conditions. - Vapour can form explosive mixtures with air. - Formation of explosive mixtures with: oxidising agents, nitrogen oxides (NOx), chlorates, nitric acid, sulphuric acid. - Exothermic reactions with: reducing agents, acids, acid halides, concentrated alkali (lye). - Violent reactions with: alkali metals, alkaline earth metals.

## state

state : liquid

form : liquid

## storage

safe_handling : - Avoid inhalation of the product.
- Avoid contact with eyes and skin.
- Wear protective gloves, protective clothing and eye/face protection.
- Use an extractor hood (laboratory).
- If handled uncovered, arrange local exhaust ventilation.
- If local exhaust ventilation is not possible or insufficient, ventilate the entire working area by technical means.
- Keep away from heat, hot surfaces, sparks, open flames and other ignition sources; no smoking.
- Take precautionary measures against static discharges.
- Use usual measures for fire prevention.
- Due to the danger of explosion, prevent leakage of vapours into cellars, flues and ditches.
- Wash hands before breaks and after work.
- Avoid contact with eyes and skin; when using do not eat, drink or smoke.
- Provide an eye shower and label its location conspicuously.

safe_storage : - Recommended storage temperature: **15 – 25 °C** - Storage class: **3** - Keep the container tightly closed and in a well‑ventilated place. - Keep cool and protect from sunlight. - Store in a place accessible only by authorized persons. - Keep/Store away from combustible materials. - Ground and bond the container and receiving equipment. - Provide adequate ventilation.

specific_end_use : Relevant identified uses: General chemical reagent

## transport

ADR : 3 (6.1)

RID : 3 (6.1)

ADN : -

IMDG : 3 (6.1)

IATA : 3 (6.1)

UN : 1230

## Validations

### Product

name : Product

role : Check if the product is compliant with all the validators

#### information

No information available

#### missing_codes

overall_result : INVALID

reference_data : None

result : INVALID

### ProductLoad

name : ProductLoad

role : Check if the product information has been retrieved correctly

#### information

WARNING : Substances without CAS or EC numbers are omitted

#### missing_codes

reference_data : None

result : UNKNOWN

### Exposure

name : Exposure

role : Checks the Substance exposure and labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms

#### information

H225 : code: H225 exposition: danger: Label elements for flammable liquids text: Liquide et vapeurs très inflammables.

H301 : code: H301 exposition: oral danger: Acute toxicity label elements text: Toxique en cas d’ingestion.

H311 : code: H311 exposition: dermal danger: Acute toxicity label elements text: Toxique par contact cutané.

H331 : code: H331 exposition: inhalation danger: Acute toxicity label elements text: Toxique par inhalation.

H370 : code: H370 exposition: danger: Label elements for specific target organ toxicity after single exposure text: Risque avéré d'effets graves pour les organes.

#### missing_codes

reference_data : None

result : AVAILABLE

### Labeling

name : Labeling

role : Checks the Substance labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms

#### information

###### pictograms

GHS08, GHS02, GHS06

signal_word : Danger

#### missing_codes

reference_data : None

result : AVAILABLE

### Precautionary

name : Precautionary

role : Checks the Substance exposure and labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms

#### information

P210 : code: P210 text: P210

P243 : code: P243 text: Prendre des mesures de précaution contre les décharges électrostatiques.

P280 : code: P280 text: Porter des gants de protection/des vêtements de protection/un équipement de protection des yeux/ du visage.

P302+P352 : code: P302+P352 text: EN CAS DE CONTACT AVEC LA PEAU:

P304+P340 : code: P304+P340 text: EN CAS D’INHALATION:

P308+P310 : code: P308+P310 text: EN CAS d’exposition prouvée ou suspectée:

#### missing_codes

reference_data : None

result : AVAILABLE

### PCode

name : PCode

role : Check if the P-codes of a product are valid based on its H-codes

#### information

Reference Codes : P210, P233, P240, P241, P242, P243, P260, P261, P264, P270, P271, P280, P301 + P310, P302 + P352, P303 + P361 + P353, P304 + P340, P308 + P311, P311, P312, P321, P330, P361 + P364, P370 + P378, P403 + P233, P403 + P235, P405, P501

Actual Codes : P210, P243, P280, P302+P352, P304+P340, P308+P310

Codes in both sets : P210, P243, P280

reason : The result is invalid because there are codes in the reference data but not in the actual data

Missing Codes : P233, P240, P241, P242, P260, P261, P264, P270, P271, P301 + P310, P302 + P352, P303 + P361 + P353, P304 + P340, P308 + P311, P311, P312, P321, P330, P361 + P364, P370 + P378, P403 + P233, P403 + P235, P405, P501

#### missing_codes

P233, P240, P241, P242, P260, P261, P264, P270, P271, P301 + P310, P302 + P352, P303 + P361 + P353, P304 + P340, P308 + P311, P311, P312, P321, P330, P361 + P364, P370 + P378, P403 + P233, P403 + P235, P405, P501

reference_data : None

result : INVALID

### Classification

name : Classification

role : Check the classification of a product based on its pH and substances concentrations

#### information

No information available

#### missing_codes

reference_data : None

result : VALID

## Methanol AnalaR NORMAPUR® Reag. Ph.Eur., ACS Analytical Reagent

cas : 67-66-1

name : Methanol AnalaR NORMAPUR® Reag. Ph.Eur., ACS Analytical Reagent

### h_codes

H370, H371

concentrations : greater or equal to 3.0 and less or equal to 10.0

ec : None

## Validations

### HazardStatement

name : HazardStatement

role : Check if the H-codes of a substance are valid based on its CAS number by comparing them to a reference data set from ECHA CLH

#### information

Reference Codes :

Actual Codes : H370, H371

Codes in both sets :

reason : The result is valid because all codes from the reference data are found in the actual data

#### missing_codes

result : VALID

### POP

name : POP

role : Check if the product must be compliant with the POP regulations

#### information

No information available

#### missing_codes

result : NOT_REGULATED

### REACH

name : REACH

role : Check if the product must be compliant with the REACH regulations according to REACH Annex XVII and XIV

#### information

No information available

#### missing_codes

result : NOT_REGULATED

### COBET

name : COBET

role : Check if the product must be compliant with the COBET regulations

#### information

No information available

#### missing_codes

result : NOT_REGULATED

### RPB

name : RPB

role : Check if the product must be compliant with the RPB regulations

#### information

No information available

#### missing_codes

result : NOT_REGULATED

### SEVESO

name : SEVESO

role : Check if the product must be compliant with the CEVESO regulations

#### information

regulation : SEVESO

substance : Methanol AnalaR NORMAPUR® Reag. Ph.Eur., ACS Analytical Reagent

h_code : H370

###### categories

code : H3

section : H

label : H3 TOXICITÉ SPÉCIFIQUE POUR CERTAINS ORGANES CIBLES (STOT) – EXPOSITION UNIQUE STOT SE Catégorie 1

threshold_low : 50.0

threshold_high : 200.0

unit : tonnes

#### missing_codes

result : REGULATED

### Exposure

name : Exposure

role : Checks the Substance exposure and labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms

#### information

H370 : code: H370 exposition: danger: Label elements for specific target organ toxicity after single exposure text: Risque avéré d'effets graves pour les organes.

H371 : code: H371 exposition: danger: Label elements for specific target organ toxicity after single exposure text: Risque présumé d'effets graves pour les organes.

#### missing_codes

result : AVAILABLE

### Labeling

name : Labeling

role : Checks the Substance labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms

#### information

###### pictograms

GHS08

signal_word : Danger

#### missing_codes

result : AVAILABLE

### INRS

name : INRS

#### information

WARNING : No INRS data found for Methanol AnalaR NORMAPUR® Reag. Ph.Eur., ACS Analytical Reagent

#### missing_codes

result : NOT_AVAILABLE

role : None

### CMR

name : CMR

role : Check if the product must be compliant with the CMR regulations

#### information

No information available

#### missing_codes

result : NOT_REGULATED

## Ethanol

cas : 67-56-1

ec : 200-659-6

name : Ethanol

### h_codes

H225, H301, H311, H331, H370**

concentrations : strictly greater than 0.0 and strictly less than 0.0

## Validations

### HazardStatement

name : HazardStatement

role : Check if the H-codes of a substance are valid based on its CAS number by comparing them to a reference data set from ECHA CLH

#### information

Reference Codes : H225, H301, H311, H331, H370**

Actual Codes :

Codes in both sets :

reason : The result is invalid because there are codes in the reference data but not in the actual data

Missing Codes : H225, H301, H311, H331, H370**

WARNING : Added Missing Codes ['H225', 'H301', 'H311', 'H331', 'H370**'] to Ethanol

###### New codes are now

H225, H301, H311, H331, H370**

#### missing_codes

H225, H301, H311, H331, H370**

result : INVALID

### POP

name : POP

role : Check if the product must be compliant with the POP regulations

#### information

No information available

#### missing_codes

result : NOT_REGULATED

### REACH

name : REACH

role : Check if the product must be compliant with the REACH regulations according to REACH Annex XVII and XIV

#### information

regulation : REACH Annex XVII (restrictions)

substance : Ethanol

entries : 1

#### missing_codes

result : REGULATED

### COBET

name : COBET

role : Check if the product must be compliant with the COBET regulations

#### information

vle-ppm : 200.0

vle-mg-m3 : 266.0

vle-courte-ppm : 250.0

vle-courte-mg-m3 : 333.0

#### missing_codes

result : REGULATED

### RPB

name : RPB

role : Check if the product must be compliant with the RPB regulations

#### information

No information available

#### missing_codes

result : NOT_REGULATED

### SEVESO

name : SEVESO

role : Check if the product must be compliant with the CEVESO regulations

#### information

regulation : SEVESO

substance : Ethanol

h_code : H225

###### categories

code : P5a

section : P

label : P5a LIQUIDES INFLAMMABLES — Liquides inflammables, catégorie 1, ou — liquides inflammables de catégorie 2 ou 3, maintenus à une température supérieure à leur point d'ébullition, ou — autres liquides dont le point d'éclair est inférieur ou égal à 60 °C, maintenus à une température supérieure à leur point d'ébullition (voir note 12)

threshold_low : 10.0

threshold_high : 50.0

unit : tonnes

code : P5b

section : P

label : P5b LIQUIDES INFLAMMABLES — Liquides inflammables de catégorie 2 ou 3 dont les conditions particulières de traitement, telles qu'une pression ou une température élevée, peuvent représenter des dangers d'accidents majeurs, ou — autres liquides ayant un point d'éclair inférieur ou égal à 60 °C, dont les conditions particulières de traitement, telles qu'une pression ou une température élevée, peuvent représenter des dangers d'accidents majeurs (voir note 12)

threshold_low : 50.0

threshold_high : 200.0

unit : tonnes

code : P5c

section : P

label : P5c LIQUIDES INFLAMMABLES Liquides inflammables de catégorie 2 ou 3 non couverts par les catégories P5a et P5b

threshold_low : 5000.0

threshold_high : 50000.0

unit : tonnes

regulation : SEVESO

substance : Ethanol

h_code : H301

###### categories

code : H2

section : H

label : H2 TOXICITÉ AIGUË — Catégorie 2, toutes voies d'exposition — Catégorie 3, exposition par inhalation (voir note 7)

threshold_low : 50.0

threshold_high : 200.0

unit : tonnes

regulation : SEVESO

substance : Ethanol

h_code : H311

###### categories

code : H2

section : H

label : H2 TOXICITÉ AIGUË — Catégorie 2, toutes voies d'exposition — Catégorie 3, exposition par inhalation (voir note 7)

threshold_low : 50.0

threshold_high : 200.0

unit : tonnes

regulation : SEVESO

substance : Ethanol

h_code : H331

###### categories

code : H2

section : H

label : H2 TOXICITÉ AIGUË — Catégorie 2, toutes voies d'exposition — Catégorie 3, exposition par inhalation (voir note 7)

threshold_low : 50.0

threshold_high : 200.0

unit : tonnes

#### missing_codes

result : REGULATED

### Exposure

name : Exposure

role : Checks the Substance exposure and labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms

#### information

H225 : code: H225 exposition: danger: Flam. Liq. text: Liquide et vapeurs très inflammables.

H301 : code: H301 exposition: oral danger: Acute Tox. text: Toxique en cas d’ingestion.

H311 : code: H311 exposition: dermal danger: Acute Tox. text: Toxique par contact cutané.

H331 : code: H331 exposition: inhalation danger: Acute Tox. text: Toxique par inhalation.

H370** : code: H370** exposition: danger: STOT SE text: Risque avéré d'effets graves pour les organes.

#### missing_codes

result : AVAILABLE

### Labeling

name : Labeling

role : Checks the Substance labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms

#### information

###### pictograms

GHS08, GHS02, GHS06

signal_word : Danger

#### missing_codes

result : AVAILABLE

### INRS

name : INRS

#### information

fiche : FICHEFévrier 2018Fiche n°5 - MéthanolFiche présentant l'essentiel des données d'hygiène et de sécurité relatives à« Méthanol »avec un rappel de la réglementation française et des recommandations techniques et médicales.En savoir plus

url : https://www.inrs.fr/accueil/publications/bdd/fichetox/fiche.html?refINRS=FICHETOX_5

###### sections

Généralités, Caractéristiques, VLEPMesurage, Incendie - Explosion[1-4, 7, 8], Pathologie - Toxicologie, Règlementation, Recommandations, Bibliographie

#### missing_codes

result : AVAILABLE

role : None

### CMR

name : CMR

role : Check if the product must be compliant with the CMR regulations

#### information

No information available

#### missing_codes

result : NOT_REGULATED