date : 2022-08-24
language_code : en
name : methanolvwr20847
ph : 7
euh_codes
expositions
code: H225 exposition: danger: Label elements for flammable liquids text: Liquide et vapeurs très inflammables.
code: H301 exposition: oral danger: Acute toxicity label elements text: Toxique en cas d’ingestion.
code: H311 exposition: dermal danger: Acute toxicity label elements text: Toxique par contact cutané.
code: H331 exposition: inhalation danger: Acute toxicity label elements text: Toxique par inhalation.
code: H370 exposition: danger: Label elements for specific target organ toxicity after single exposure text: Risque avéré d'effets graves pour les organes.
h_codes
H225, H301, H311, H331, H370
information
p_codes
P210, P243, P280, P302+P352, P304+P340, P308+P310
precautions
code: P210 text: P210
code: P243 text: Prendre des mesures de précaution contre les décharges électrostatiques.
code: P280 text: Porter des gants de protection/des vêtements de protection/un équipement de protection des yeux/ du visage.
code: P302+P352 text: EN CAS DE CONTACT AVEC LA PEAU:
code: P304+P340 text: EN CAS D’INHALATION:
code: P308+P310 text: EN CAS d’exposition prouvée ou suspectée:
age : 3
body
skin : **Skin contact** • Wash the affected area immediately with plenty of water and soap. • Remove contaminated, saturated clothing right away. • If skin reactions occur, consult a physician.
eyes : **Eye contact** • Flush the eye(s) immediately with plenty of flowing water for 10–15 minutes while holding the eyelids apart. • Remove contact lenses if present and easy to do. • Continue rinsing and consult an ophthalmologist; protect the uninjured eye.
ingestion : **Ingestion** • Call a poison centre/doctor immediately. • Do **not** induce vomiting. • Rinse the mouth thoroughly with water. • Give nothing to eat or drink.
inhalation : **Inhalation** • Call a poison centre/doctor immediately. • Move the person to fresh air and keep them warm and at rest. • If breathing is irregular or stops, give artificial respiration.
company
name : VWR International Ltd.
fire
water : True
foam : False
powder : True
co2 : True
other : Nitrogen
labellings
explosive : False
flammable : True
oxidising : False
gaz : False
corrosive : False
acute : True
health : False
serious : True
hazardous : False
warning : Danger
protection
skin : -
eyes : **Eye / face protection** \| Eye glasses with side protection \| Must conform to DIN‑EN 166. Recommended model: **VWR 111‑0432**.
respiratory : **Respiratory protection** \| Full‑, half‑ or quarter‑face masks (DIN EN 136/140) \| Required when aerosol or mist formation occurs. Recommended model: **VWR 111‑0206**. Filter material: **AXP3** (recommended model: **VWR 111‑8932**).
hands : **Gloves – short‑term hand contact** \| Nitrile rubber (NBR) \| Thickness: **0.38 mm**. Breakthrough time: **not specified**. Recommended model: **VWR 112‑1381**.
**Gloves – long‑term hand contact** \| Butyl rubber (butyl caoutchouc) \| Thickness: **0.30 mm**. Breakthrough time: **> 480 min**. Recommended model: **VWR 112‑3779**.
clothing : **Protective clothing** \| CE‑labelled clothing with the four control digits \| Must be worn when handling the chemical. No further material or thickness details are given in the document.
stability
stability : The product is chemically stable under standard ambient conditions (room temperature).
reaction : - The material is non‑reactive under normal conditions. - Vapour can form explosive mixtures with air. - Formation of explosive mixtures with: oxidising agents, nitrogen oxides (NOx), chlorates, nitric acid, sulphuric acid. - Exothermic reactions with: reducing agents, acids, acid halides, concentrated alkali (lye). - Violent reactions with: alkali metals, alkaline earth metals.
state
state : liquid
form : liquid
storage
safe_handling : - Avoid inhalation of the product.
- Avoid contact with eyes and skin.
- Wear protective gloves, protective clothing and eye/face protection.
- Use an extractor hood (laboratory).
- If handled uncovered, arrange local exhaust ventilation.
- If local exhaust ventilation is not possible or insufficient, ventilate the entire working area by technical means.
- Keep away from heat, hot surfaces, sparks, open flames and other ignition sources; no smoking.
- Take precautionary measures against static discharges.
- Use usual measures for fire prevention.
- Due to the danger of explosion, prevent leakage of vapours into cellars, flues and ditches.
- Wash hands before breaks and after work.
- Avoid contact with eyes and skin; when using do not eat, drink or smoke.
- Provide an eye shower and label its location conspicuously.
safe_storage : - Recommended storage temperature: **15 – 25 °C** - Storage class: **3** - Keep the container tightly closed and in a well‑ventilated place. - Keep cool and protect from sunlight. - Store in a place accessible only by authorized persons. - Keep/Store away from combustible materials. - Ground and bond the container and receiving equipment. - Provide adequate ventilation.
specific_end_use : Relevant identified uses: General chemical reagent
transport
ADR : 3 (6.1)
RID : 3 (6.1)
ADN : -
IMDG : 3 (6.1)
IATA : 3 (6.1)
UN : 1230
Validations
Product
name : Product
role : Check if the product is compliant with all the validators
information
No information available
missing_codes
overall_result : INVALID
reference_data : None
result : INVALID
ProductLoad
name : ProductLoad
role : Check if the product information has been retrieved correctly
information
WARNING : Substances without CAS or EC numbers are omitted
missing_codes
reference_data : None
result : UNKNOWN
Exposure
name : Exposure
role : Checks the Substance exposure and labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms
information
H225 : code: H225 exposition: danger: Label elements for flammable liquids text: Liquide et vapeurs très inflammables.
H301 : code: H301 exposition: oral danger: Acute toxicity label elements text: Toxique en cas d’ingestion.
H311 : code: H311 exposition: dermal danger: Acute toxicity label elements text: Toxique par contact cutané.
H331 : code: H331 exposition: inhalation danger: Acute toxicity label elements text: Toxique par inhalation.
H370 : code: H370 exposition: danger: Label elements for specific target organ toxicity after single exposure text: Risque avéré d'effets graves pour les organes.
missing_codes
reference_data : None
result : AVAILABLE
Labeling
name : Labeling
role : Checks the Substance labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms
information
pictograms
GHS08, GHS02, GHS06
signal_word : Danger
missing_codes
reference_data : None
result : AVAILABLE
Precautionary
name : Precautionary
role : Checks the Substance exposure and labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms
information
P210 : code: P210 text: P210
P243 : code: P243 text: Prendre des mesures de précaution contre les décharges électrostatiques.
P280 : code: P280 text: Porter des gants de protection/des vêtements de protection/un équipement de protection des yeux/ du visage.
P302+P352 : code: P302+P352 text: EN CAS DE CONTACT AVEC LA PEAU:
P304+P340 : code: P304+P340 text: EN CAS D’INHALATION:
P308+P310 : code: P308+P310 text: EN CAS d’exposition prouvée ou suspectée:
missing_codes
reference_data : None
result : AVAILABLE
PCode
name : PCode
role : Check if the P-codes of a product are valid based on its H-codes
information
Reference Codes : P210, P233, P240, P241, P242, P243, P260, P261, P264, P270, P271, P280, P301 + P310, P302 + P352, P303 + P361 + P353, P304 + P340, P308 + P311, P311, P312, P321, P330, P361 + P364, P370 + P378, P403 + P233, P403 + P235, P405, P501
Actual Codes : P210, P243, P280, P302+P352, P304+P340, P308+P310
Codes in both sets : P210, P243, P280
reason : The result is invalid because there are codes in the reference data but not in the actual data
Missing Codes : P233, P240, P241, P242, P260, P261, P264, P270, P271, P301 + P310, P302 + P352, P303 + P361 + P353, P304 + P340, P308 + P311, P311, P312, P321, P330, P361 + P364, P370 + P378, P403 + P233, P403 + P235, P405, P501
missing_codes
P233, P240, P241, P242, P260, P261, P264, P270, P271, P301 + P310, P302 + P352, P303 + P361 + P353, P304 + P340, P308 + P311, P311, P312, P321, P330, P361 + P364, P370 + P378, P403 + P233, P403 + P235, P405, P501
reference_data : None
result : INVALID
Classification
name : Classification
role : Check the classification of a product based on its pH and substances concentrations
information
No information available
missing_codes
reference_data : None
result : VALID
Methanol AnalaR NORMAPUR® Reag. Ph.Eur., ACS Analytical Reagent
cas : 67-66-1
name : Methanol AnalaR NORMAPUR® Reag. Ph.Eur., ACS Analytical Reagent
h_codes
H370, H371
concentrations : greater or equal to 3.0 and less or equal to 10.0
ec : None
Validations
HazardStatement
name : HazardStatement
role : Check if the H-codes of a substance are valid based on its CAS number by comparing them to a reference data set from ECHA CLH
information
Reference Codes :
Actual Codes : H370, H371
Codes in both sets :
reason : The result is valid because all codes from the reference data are found in the actual data
missing_codes
result : VALID
POP
name : POP
role : Check if the product must be compliant with the POP regulations
information
No information available
missing_codes
result : NOT_REGULATED
REACH
name : REACH
role : Check if the product must be compliant with the REACH regulations according to REACH Annex XVII and XIV
information
No information available
missing_codes
result : NOT_REGULATED
COBET
name : COBET
role : Check if the product must be compliant with the COBET regulations
information
No information available
missing_codes
result : NOT_REGULATED
RPB
name : RPB
role : Check if the product must be compliant with the RPB regulations
information
No information available
missing_codes
result : NOT_REGULATED
SEVESO
name : SEVESO
role : Check if the product must be compliant with the CEVESO regulations
information
regulation : SEVESO
substance : Methanol AnalaR NORMAPUR® Reag. Ph.Eur., ACS Analytical Reagent
h_code : H370
categories
code : H3
section : H
label : H3 TOXICITÉ SPÉCIFIQUE POUR CERTAINS ORGANES CIBLES (STOT) – EXPOSITION UNIQUE STOT SE Catégorie 1
threshold_low : 50.0
threshold_high : 200.0
unit : tonnes
missing_codes
result : REGULATED
Exposure
name : Exposure
role : Checks the Substance exposure and labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms
information
H370 : code: H370 exposition: danger: Label elements for specific target organ toxicity after single exposure text: Risque avéré d'effets graves pour les organes.
H371 : code: H371 exposition: danger: Label elements for specific target organ toxicity after single exposure text: Risque présumé d'effets graves pour les organes.
missing_codes
result : AVAILABLE
Labeling
name : Labeling
role : Checks the Substance labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms
information
pictograms
GHS08
signal_word : Danger
missing_codes
result : AVAILABLE
INRS
name : INRS
information
WARNING : No INRS data found for Methanol AnalaR NORMAPUR® Reag. Ph.Eur., ACS Analytical Reagent
missing_codes
result : NOT_AVAILABLE
role : None
CMR
name : CMR
role : Check if the product must be compliant with the CMR regulations
information
No information available
missing_codes
result : NOT_REGULATED
Ethanol
cas : 67-56-1
ec : 200-659-6
name : Ethanol
h_codes
H225, H301, H311, H331, H370**
concentrations : strictly greater than 0.0 and strictly less than 0.0
Validations
HazardStatement
name : HazardStatement
role : Check if the H-codes of a substance are valid based on its CAS number by comparing them to a reference data set from ECHA CLH
information
Reference Codes : H225, H301, H311, H331, H370**
Actual Codes :
Codes in both sets :
reason : The result is invalid because there are codes in the reference data but not in the actual data
Missing Codes : H225, H301, H311, H331, H370**
WARNING : Added Missing Codes ['H225', 'H301', 'H311', 'H331', 'H370**'] to Ethanol
New codes are now
H225, H301, H311, H331, H370**
missing_codes
H225, H301, H311, H331, H370**
result : INVALID
POP
name : POP
role : Check if the product must be compliant with the POP regulations
information
No information available
missing_codes
result : NOT_REGULATED
REACH
name : REACH
role : Check if the product must be compliant with the REACH regulations according to REACH Annex XVII and XIV
information
regulation : REACH Annex XVII (restrictions)
substance : Ethanol
entries : 1
missing_codes
result : REGULATED
COBET
name : COBET
role : Check if the product must be compliant with the COBET regulations
information
vle-ppm : 200.0
vle-mg-m3 : 266.0
vle-courte-ppm : 250.0
vle-courte-mg-m3 : 333.0
missing_codes
result : REGULATED
RPB
name : RPB
role : Check if the product must be compliant with the RPB regulations
information
No information available
missing_codes
result : NOT_REGULATED
SEVESO
name : SEVESO
role : Check if the product must be compliant with the CEVESO regulations
information
regulation : SEVESO
substance : Ethanol
h_code : H225
categories
code : P5a
section : P
label : P5a LIQUIDES INFLAMMABLES — Liquides inflammables, catégorie 1, ou — liquides inflammables de catégorie 2 ou 3, maintenus à une température supérieure à leur point d'ébullition, ou — autres liquides dont le point d'éclair est inférieur ou égal à 60 °C, maintenus à une température supérieure à leur point d'ébullition (voir note 12)
threshold_low : 10.0
threshold_high : 50.0
unit : tonnes
code : P5b
section : P
label : P5b LIQUIDES INFLAMMABLES — Liquides inflammables de catégorie 2 ou 3 dont les conditions particulières de traitement, telles qu'une pression ou une température élevée, peuvent représenter des dangers d'accidents majeurs, ou — autres liquides ayant un point d'éclair inférieur ou égal à 60 °C, dont les conditions particulières de traitement, telles qu'une pression ou une température élevée, peuvent représenter des dangers d'accidents majeurs (voir note 12)
threshold_low : 50.0
threshold_high : 200.0
unit : tonnes
code : P5c
section : P
label : P5c LIQUIDES INFLAMMABLES Liquides inflammables de catégorie 2 ou 3 non couverts par les catégories P5a et P5b
threshold_low : 5000.0
threshold_high : 50000.0
unit : tonnes
regulation : SEVESO
substance : Ethanol
h_code : H301
categories
code : H2
section : H
label : H2 TOXICITÉ AIGUË — Catégorie 2, toutes voies d'exposition — Catégorie 3, exposition par inhalation (voir note 7)
threshold_low : 50.0
threshold_high : 200.0
unit : tonnes
regulation : SEVESO
substance : Ethanol
h_code : H311
categories
code : H2
section : H
label : H2 TOXICITÉ AIGUË — Catégorie 2, toutes voies d'exposition — Catégorie 3, exposition par inhalation (voir note 7)
threshold_low : 50.0
threshold_high : 200.0
unit : tonnes
regulation : SEVESO
substance : Ethanol
h_code : H331
categories
code : H2
section : H
label : H2 TOXICITÉ AIGUË — Catégorie 2, toutes voies d'exposition — Catégorie 3, exposition par inhalation (voir note 7)
threshold_low : 50.0
threshold_high : 200.0
unit : tonnes
missing_codes
result : REGULATED
Exposure
name : Exposure
role : Checks the Substance exposure and labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms
information
H225 : code: H225 exposition: danger: Flam. Liq. text: Liquide et vapeurs très inflammables.
H301 : code: H301 exposition: oral danger: Acute Tox. text: Toxique en cas d’ingestion.
H311 : code: H311 exposition: dermal danger: Acute Tox. text: Toxique par contact cutané.
H331 : code: H331 exposition: inhalation danger: Acute Tox. text: Toxique par inhalation.
H370** : code: H370** exposition: danger: STOT SE text: Risque avéré d'effets graves pour les organes.
missing_codes
result : AVAILABLE
Labeling
name : Labeling
role : Checks the Substance labeling data. see https://echa.europa.eu/documents/10162/2324906/clp_labelling_en.pdf/89628d94-573a-4024-86cc-0b4052a74d65 see https://echa.europa.eu/regulations/clp/clp-pictograms
information
pictograms
GHS08, GHS02, GHS06
signal_word : Danger
missing_codes
result : AVAILABLE
INRS
name : INRS
information
fiche : FICHEFévrier 2018Fiche n°5 - MéthanolFiche présentant l'essentiel des données d'hygiène et de sécurité relatives à« Méthanol »avec un rappel de la réglementation française et des recommandations techniques et médicales.En savoir plus
url : https://www.inrs.fr/accueil/publications/bdd/fichetox/fiche.html?refINRS=FICHETOX_5
sections
Généralités, Caractéristiques, VLEPMesurage, Incendie - Explosion[1-4, 7, 8], Pathologie - Toxicologie, Règlementation, Recommandations, Bibliographie
missing_codes
result : AVAILABLE
role : None
CMR
name : CMR
role : Check if the product must be compliant with the CMR regulations
information
No information available
missing_codes
result : NOT_REGULATED